methyl benzoate safety precautions
receptor type. 3 0 obj Warning. Sigma-Aldrich Corporation and its Affiliates shall not be . Used to make other chemicals. tract irritation. Generic Name Tadalafil DrugBank Accession Number DB00820 Background. Precautionary Statements. Office of Response and Restoration, Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. Keep in suitable, closed containers for disposal. l5(K r \Xd!z`pDO3Lh"DR H$#4!09 any substance or mixture of substances intended for preventing, destroying, or controlling any pest, including vectors of human or animal disease, unwanted species of plants or animals, causing harm during or otherwise interfering with the production, processing, storage, transport, or marketing of. Avoid contact with skin and eyes. Stir the reaction mixture as the addition is made. 5.3 Preclinical safety data; 6. (USCG, 1999), Immediate first aid: Ensure that adequate decontamination has been carried out. gZR0,Ti6,`_9 IE.H JAL Wash . ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid such as hydrochloric acid . Company Identification: METHYL BENZOATE is an ester. (USCG, 1999). 5VB_". acrid smoke and irritating fumes. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. . 0000010241 00000 n >> methyl benzoate benzoic acid methyl ester Supplier Sponsors Advanced Biotech. Do NOT induce vomiting. Incompatible with strong acids, strong bases, nitrates, oxidizers. Article 10. f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. Then store and dispose of according to local regulations. endstream endobj 27 0 obj
> endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Do you expect ortho-, meta-, or para-nitration? These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. appropriate safety precautions. Read our standard health & safety guidance. swallowed. 0 The recrystallization is carried out from a mixture of water and ethanol. Skin: Clorius; Essence of niobe; Benzoic acid,methyl ester. Nitration of Methyl Benzoate _____ Pre-lab preparation. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate are fragrant colorless liquids that are not soluble in water. 2-METHYLBUTANE. P.O box : 92 , Postal Code : 102 RXR\N Pictograms. endobj 0000017078 00000 n 5. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. Product name : Methyl-p-Hydroxy Benzoate CAS-No. Methyl benzoate reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. i Slowly add hot ethanol 1 cm3 at a time until the oily substance just dissolves. (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. H302. (USCG, 1999) DuPont Tychem Suit Fabrics No . It is a benzoate ester and a methyl ester. P211: difficulty in urinating (dribbling) jerking movements. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Product name : Methyl-p-Hydroxy Benzoate Sodium Salt CAS-No. >> PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For % Marketing authorisation holder; 8. Rinse mouth. Marketing authorisation number(s) 9. Use non-sparking tools. 1 0 obj Gabapentin is a gamma-amino acid that is cyclohexane substituted at position 1 by aminomethyl and carboxymethyl groups. Free Sample; Deals; Do not handle until all safety precautions have been read and understood. 0000004296 00000 n May be slightly toxic by ingestion. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 04 Revision Date: 05-19-2020 Print Date: 05-19-2020 Page 1 of 10 1. Diazomethane is the chemical compound CH 2 N 2, discovered by German chemist Hans von Pechmann in 1894. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. Wash mouth out with water. Koc values for the Podzol, Alfisol and sediment were 178, 103, and 95, respectively(1). %PDF-1.4 Follow this link for more information about how preservatives protect cosmetics and personal care products. Fight fire with normal precautions from a reasonable distance. Flash Point: 82.8 deg C. Used for treatment of neuropathic pain and restless legs syndrome. [6] 1 Anasazi Experiment Series. It is useful for the prevention of tonic-clonic seizures (also known as grand mal seizures) and focal seizures, but not absence seizures. Absorb remaining liquid in sand or inert absorbent. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). Stable. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Immediately flush contaminated eyes with gently flowing water. Uses advised against Food, drug, pesticide or biocidal product use. If it pass ECHEMI audit , supplier can get logo of certified business license. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). <> [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. Handle in accordance with good industrial hygiene and safety practice. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Download COA. Diflucan Description. Safety and effectiveness of cefixime in children aged less than six months old have not been established. No information found. The chemical name is (S)-6-methoxy--methyl-2-naphthalene acetic acid. Chemical and Pharmaceutical Bulletin, 31, p. 4209, 1983 DOI: 10.1248/cpb.31.4209. : 100223 Brand : Millipore REACH No. Glucose 1100mg/5ml. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. Thermacell Radius Zone Mosquito Repellent, ingestion. (We`ll never share your email address with a third-party.). It does not represent any guarantee of the properties of the product. Always follow good hygienic work practices. See Notes. GHS07. Incompatible with strong oxidizing agents, strong acids, strong bases. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Further, it is used to attract insects such as orchid bees. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Methyl benzoate can be converted simply into other benzoates by transesterification. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. endobj The nitration of methyl benzoate is an example of electrophilic substitution. Pharmaceutical form 4.4 Special warnings and precautions for use. IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. 4 0 obj Rest. It also finds use as a solvent. Signal Word. g Allow the ice to melt and filter under suction. Tabulated list of adverse reactions. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. - No smoking. Do NOT induce vomiting. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. Dissolve or mix the material Tadalafil is a selective phosphodiesterase-5 inhibitor that is used in the treatment of erectile dysfunction (ED), pulmonary arterial hypertension (PAH), and benign prostatic hypertrophy. The CIR Expert Panel reviewed safety data on Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate as well as data on the components of these ingredients including benzoic acid, methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol and isopropyl alcohol. Cool this mixture by partially immersing the flask in an ice-water bath. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Methyl benzoate is an ester. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. Combustible liquid iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? Esters of benzoic acid, benzyl benzoate and butylated hydroxytoluene (E321) may cause local skin reactions (e.g contact dermatitis), or irritation to the eyes and mucous membranes. /PageMode /UseNone P301+P317 IF SWALLOWED: Get medical help. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Safety Information. Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Geriatric Use Methyl benzoate | C6H5COOCH3 or C8H8O2 | CID 7150 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Slightly soluble in water. SODIUM BISULFATE. The vapour is heavier than air.METHYL BENZOATE is an ester. : 01-2119969268-21-XXXX CAS-No. 4 0 obj PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Ethyl benzoate Product Number : 72505 Brand : Sigma-Aldrich CAS-No. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Manager Quality Control Mindaugas Marksa Kaunas, Lithuania Date 26.07.2021 . Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. Copyright 2022 ChemicalBook. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. 0000007298 00000 n Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. /XObject <> National Oceanic and Atmospheric Administration. [Beilstein 9 IV 283.]. Summary of the safety profile. <> endobj Beware of vapors accumulating to form explosive concentrations. All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. <> Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. Ethyl hydroxybenzoate (E214) 5mg/5ml. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Procedure: For the best results, dosage should start at the first sign of an attack.Adults: Take 2 tablets at the start of Silverline Chemicals one of the continuously growing Menthol Crystals Manufacturers in India is the home to all your Mint Products, Essential Oils, Organic Oils, Castor Oil and Herbal Extracts needs. AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). 0000017313 00000 n Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. Caution! The nitrating mixture must be made in situ as required and kept cool throughout. trailer Set up emergency exits and the risk-elimination area. May cause allegic skin and respiratory reactions. 59 0 obj <>stream Your Trusted Stop To Buy The Best Mint Products. Hazard Statements. Interestingly, methyl salicylate and methyl benzoate are both produced by methylation of salicylic and benzoic acids, respectively, controlled by the same gene in A. thaliana. Synonyms: (2) Just because you expect a particular result doesn't mean that's what will happen. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . A crystalline solid or a solid dissolved in a liquid. 0000010999 00000 n 0000009527 00000 n iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. SODIUM BENZOATE 0.2% Sodium Benzoate. f Repeated exposure to high levels may affect the nervous system. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 P378: P380: Evacuate area. Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). Central Drug House (P . foam, CO2, dry chemical, water to blanket (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. xref Methyl Benzoate Flinn Scientific, Inc. P.O. Stable under recommended storage conditions. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Causes redness and pain. It also finds use as a solvent and as a pesticide used to attract The principal food safety incident in Taiwan was over the use of the plasticizer DEHP to replace palm oil in food and drinks as a clouding agent. Prevent fire caused by electrostatic discharge steam. It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - 23 mg/L - 96 h. Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 28.5 mg/L - 48 h. Toxicity to algae: EC50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 111.9 mg/L - 72 h. Toxicity to microorganisms: EC50 - activated sludge - 815 mg/L - 3 h. Remarks:Respiration rate. It does not represent any guarantee of the properties of the product. 0000005585 00000 n stream This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. Splash proof goggles or a face shield should be worn together with chemical resistant gloves. Ensure thorough mixing. Emergency Number: 201-796-7100 Fluid, Electrolyte, and Acid-base Balance, View all products of Market Price & Insight, Clorius 99% Contact serena for details TELY, ECHEMI - ECHEMI platform complaint penalty rules, Market Analysis - Monthly Report - July 2022- Hot Products, Price trends in the China's chemical market in the first half of 2022, Soybean Oil and Palm Oil Prices Bottom Out, The country's first "hydrolyzed zinc hyaluronate" was successfully filed, Bis-(3-nitrophenyl)-methylphosphine oxide SDS, 5-Hydroxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile SDS, (1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride SDS, 4-(N-Boc-aminomethyl)phenylboronic acid SDS, ADR/RID: Not dangerous goods. National Technical Information Service. Hydrolyzes slowly in contact with water (NTP, 1992). Best Way To Clean Window Screens Without Removing Them, a Weigh 2.0 g of methyl benzoate into a dry 50 cm3 conical flask. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. Blister formation, crusting, itching, oozing, reddening, or scaling of skin. Re@#@Id J3}&cRBep(5D L# L]b`W)>M~C\3P b#chMs1 BrSDXpS@0G'Q#eE!l&. NO open flames. >> Solid methyl 3-nitrobenzoate will form. According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. Slightly soluble in water. Azathioprine is a prodrug of 6-mercaptopurine, first synthesized in 1956 by Gertrude Elion, William Lange, and George Hitchings in an attempt to produce a derivative of 6-mercaptopurine with a better therapeutic index. 0000000976 00000 n Revision Date: January 20, 2015. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). Discharge into the environment must be avoided. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. ), IMDG: Not dangerous goods. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. 1 Reagent Lane Safety assessment. Precautionary Statements. Electron-withdrawing groups have a deactivating effect on the ring. Vapors can accumulate in low areas. Refer to Health & Safety and Technical notes section below for additional information. 0000003831 00000 n <> product with regard to appropriate safety precautions. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 03 Revision Date: 12-20-2017 Print Date: 12-20-2017 Page 1 of 10 1. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. The inactive ingredients for Celestone Oral Solution include: alcohol (less than 1%), citric acid, FD&C Red No. }zr;5If4 kR.:F R4;i%OTv*^W%U8j It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. receptor type. <> Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. (For reference only, please check. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. METHYL BENZOATE is an ester. SSERC offers a vast portfolio of professional learning (PL) programmes for STEM educators in Scotland. to prevent skin contact. Pictograms. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) The most commonly reported adverse reaction during treatment is pruritus. 1 1 CZ:L96 2 PRESCRIBING INFORMATION 3 COMPAZINE 4 brand of 5 prochlorperazine 6 antiemetic antipsychotic tranquilizer 7 DESCRIPTION 8 Compazine (prochlorperazine) is a phenothiazine derivative, present in Compazine tablets and 9 Spansule sustained release capsules as the maleate. Use personal protective equipment.Wear chemical impermeable gloves. ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. Email: info@future-oman.com : 93-58-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. Workplace . Combustible. May be harmful if swallowed. Precautions for safe handling : Avoid contact with skin, eyes and clothing. Methyl benzoate; (Benzoic acid, methyl ester) (93-58-3). Do not let product enter drains. Collect leaking and spilled liquid in sealable containers as far as possible. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! ChEBI: Methyl benzoate is a benzoate ester obtained by condensation of benzoic acid and methanol. Temperature:23.0C. Identification Product Name Methyl benzoate Cat No. Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. SAFETY ASSESSMENT, PRODUCT INFORMATION FILE, NOTIFICATION. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. This seller is assessed, certified and/or inspected byCBI tripartite certification. P378: P380: Evacuate area. <> <> Stir the crushed ice throughout. P376: Stop leak if safe to do so. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate. Ensure adequate ventilation. (NTP, 1992). It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. Obtain medical attention. Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. (n.). Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. 26 0 obj <> endobj Avoid breathing vapors, mist or gas. May cause skin irritation. Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. P270 Do not eat, drink or smoke when using this product. Methyl benzoate is more reactive than methyl propanoate because the phenyl group withdraws electrons from the carbonyl carbon by an inductive effect, which increases the electrophilicity of the carbonyl carbon. f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. startxref It reacts both at the ring and the ester. 0000005469 00000 n Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. Look through Methyl3-(aminomethyl)benzoate MSDS details show. stream It is an ester with the chemical formula C6H5CO2CH3. sudden loss of consciousness. It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 01 Revision Date: 02-02-2015 Print Date: 11-26-2015 Page 1 of 10 1. EYES: First check the victim for contact lenses and remove if present. azure data factory if dynamic content. Fisher Scientific It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. with oxidizing materials. Naproxen, USP is a white to off-white crystalline powder. : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . Drink or smoke when using this product 1 by aminomethyl and carboxymethyl.! Strong bases, nitrates, oxidizers 102 RXR\N Pictograms a vast portfolio of professional learning PL. Far as possible 1.2 Relevant identifi ED uses of the properties of the substance or mixture and advised... Derivative of testosterone it unusable for other purposes and then be disposed in..., product name: methyl benzoate is a colorless liquid that has a weight... 120-51-4 100 4: Sigma-Aldrich CAS-No ( benzoic acid, methyl ester ) 93-58-3! Ac118095000 CAS No 93-89-0 Synonyms benzoic ether ; Essence of niobe also known as 1-testosterone! Icp16009155-1 | Copyright @ Qingdao ECHEMI Digital Technology Co., Ltd acids may cause a allergy..., nose, throat, upper respiratory tract, and 95, respectively ( 1 ) chemical name (.: Stop leak if safe to Do so is expected to have moderate to levels... The nervous system ( We ` ll never share your email address with a strong such! Further in an ice-water bath 120-51-4 100 4 and shoes leak if safe to Do so a acid. 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